水体中微塑料的环境影响行为研究进展

微塑料是指一类广泛存在于环境中的粒径小于5mm的塑料颗粒的总称，当其存在于水体环境中，容易吸附其他污染物，影响它们的迁移行为，进而对生态效应产生影响。本文依据水体环境中微塑料的相关研究报道，对微塑料在水环境中的影响行为进行概述。主要从微塑料的物理、化学和生物特性在环境中的变化特性，微塑料与环境中其他污染物质的相互作用关系，以及微塑料及其复合污染体系对水生生物造成的生态效应影响等3个方面对微塑料的环境行为进行总结、归纳与阐述。最后，针对微塑料对水环境中的环境影响效应，提出了今后的研究方向与展望。     

Study of partial discharge characteristics in HFO-1234ze(E)/N2 mixtures

HFO-1234ze(E)(trans-1,3,3,3-tetrafluoropropene, chemical formula: C₃H₂F₄) is an extremely environmentally friendly SF₆ alternative gas with high electrical strength. In this paper, the partial discharge (PD) characteristics of HFO-1234ze(E)/N₂ mixtures were studied using the gas insulation test platform. The PD inception voltage of insulating gas under positive and negative half cycles of power frequency was tested. Using SF₆/N₂ mixtures as a control group, the effects of electrode spacing, mixing ratio and pressure on the insulation performance of HFO-1234ze(E)/N₂ mixtures were explored. The test results show that the PD inception voltage of the negative half-cycle of pure HFO-1234ze(E) under short electrode spacing can reach 0.96–1.04 times of pure SF₆ under different pressures; the PD inception voltage of 40%HFO-1234ze(E)/60%N₂ mixtures at 0.3 MPa is 0.67–0.89 times that of SF₆/N₂ mixtures under the same conditions, which has great application prospect.     

溢出效应和网络贴合度扰动下的二级供应链网络广告投放策略分析

为研究溢出效应和网络贴合度扰动下,二级供应链的网络广告投放策略问题,以强势制造商和两个网络零售商组成的二级供应链为研究对象,考虑产品的网络贴合度和网络广告计费特征,构建基于溢出效应的期望需求模型,通过博弈论方法给出了完全不合作、合作、半合作、战略联盟等4种模式下的均衡解,并对以上4种均衡结果进行比较分析。研究结果表明:无论在何种模式下,制造商批发价格与产品的网络贴合度成反比;固定位网络广告投资额和网络广告投资总额与产品的网络贴合度成正比,固定位网络广告投资额与溢出效应成反比;合作状态下的利润总额通常情况下较低;当产品的网络贴合度超过一定阈值范围时,采用战略联盟使得供应链成员利润最大化。     

厚煤层回采中卸压瓦斯抽采分析

以厚煤层回采中卸压瓦斯抽采为对象开展探究,结合具体工程实际,在进行瓦斯涌出预测分析的基础上,全面总结分析瓦斯抽采治理综合措施,并对其实际应用效果作出探究。结果表明,应用综合防治措施,实现了对厚煤层瓦斯的有效抽采,提升了作业的安全性和有效性。     

Automatic restraint and visual detection of fatigue crack growth when applying an anti-fatigue smart paste to bolt holes

An anti-fatigue smart paste, which consists of fine alumina particles and silicone grease with low viscosity, was applied to a bolt hole (and its periphery in some cases) in a steel plate specimen, and the effects of the smart paste on automatic restraint and visual detection of fatigue crack growth were experimentally investigated through fatigue tests. Fractographic observations using a scanning electron microscope were also carried out. As a result, approximately 20～410% increase in failure life was produced by the wedge effect of the alumina particles in the smart paste. When the smart paste was applied, remarkable black colour developed in the white paste along the paths of crack growth, exceedingly facilitating the visual detection of the crack growth.     

Insights into pyrolysis and catalytic co-pyrolysis upgrading of biomass and waste rubber seed oil to promote the formation of aromatics hydrocarbon

To solve the problem of low aromatic hydrocarbon yield and selectivity in biomass catalytic pyrolysis, we used added oxygen-containing hydrogen supplier of rubber seed oil (RSO) with a higher hydrogen-to-carbon ratio to investigate the thermal decomposition behaviors, kinetic and production distribution of biomass, cellulose and RSO with the weight ratio of 1:2 using thermogravimetric analyzer (TGA) for kinetic analysis and fixed bed reactor with the feed composition of 1.2 g: 0.4 mL/min (Biomass to RSO) for product distribution in non-catalytic and catalytic co-pyrolysis over a HZSM-5 catalyst. The results show that there was a positive synergistic interaction between biomass and RSO according to the difference in weight loss, which could decrease the formation of solid coke at the end of experiment. The addition of the HZSM-5 catalyst can markedly increase the reaction activity, accelerate the reaction rate, and the reaction Ea, leading to a substantial increase in the conversion rate; furthermore, the residual carbon content will decrease, and the activations of Cellulose + RSO + Catalyst and Biomass + RSO + Catalyst are only 50.80 kJ/mol and 62.36 kJ/mol, respectively. The kinetic analysis showed that adding a catalyst did not change the decomposition mechanism. Co-pyrolysis of biomass and RSO could effectively improve the yield and selectivity of aromatics, when the pyrolysis temperature and catalytic temperature were 550 °C and 500 °C, respectively, the mass space velocity of RSO was 0.4 mL/min, the reaction time was 30min, the yields of benzene, toluene, xylene and ethyl benzene (BTXE) were up to 78.77%, and the selectivity of benzene, toluene and xylene was much better. Finally, the coke yield was substantially lower.     

骨料粒径对混凝土动态拉伸强度及尺寸效应影响分析

骨料粒径是影响混凝土力学性能及破坏机理的重要因素。从细观角度出发,将混凝土看作由骨料颗粒、砂浆基质及界面过渡区组成的三相复合材料,考虑细观组分的应变率效应,建立了混凝土动态拉伸破坏行为研究的细观力学分析模型,模拟研究了不同骨料粒径下混凝土动态拉伸破坏行为,并揭示了动态拉伸强度的尺寸效应规律。研究表明:低应变率下骨料不发生破坏,骨料粒径对混凝土动态拉伸破坏模式及拉伸强度影响显著,且拉伸强度的尺寸效应随骨料粒径的减小而削弱;高应变率下裂缝将贯穿骨料,骨料粒径的大小对混凝土动态拉伸强度及尺寸效应影响可忽略。最后,结合应变率效应的影响机制,建立了混凝土拉伸强度的"静动态统一"尺寸效应理论公式,该公式可以较好描述各骨料粒径下混凝土动态拉伸强度与试件尺寸的定量关系。     

5种种衣剂对甘肃省小麦散黑穗病防治效果

[目的]明确5种种子包衣剂对小麦散黑穗病的防治效果及对产量的影响。[方法]于2019年在民乐县,采用播种前种子包衣处理,进行田间试验。[结果]供试种子包衣剂对小麦出苗安全,对小麦散黑穗病的防效在90.15%~97.78%之间,增产幅度在9.39%~13.05%之间。其中27%苯醚·咯·噻虫FS和15%吡·福·烯唑醇FS防病、增产作用更为显著,防效、产量和增幅分别为97.78%、8340.74 kg/hm^2、13.05%和95.93%、8200.00 kg/hm^2、11.20%。[结论]建议生产中选用27%苯醚·咯·噻虫FS和15%吡·呋·烯唑醇FS,进行种子包衣防治小麦散黑穗病。     

Freestanding graphitic carbon nitride-based carbon nanotubes hybrid membrane as electrode for lithium/polysulfides batteries

Lithium sulfur batteries have drawled worldwide attention in recent years, which benefit of its high-density energetic, low cost, and environmental benignity. Nevertheless, the shuttle effect of polysulfides and resulting self-discharge lead to capacity fade loss and poor electrochemical performance. Herein, graphitic-carbon nitride/carbon nanotubes (g-C₃N₄/CNTs) hybrid membrane is fabricated by the flow-direct vacuum filtration process. The as-prepared 3-D freestanding g-C₃N₄/CNTs membrane employed as positive current collector containing Li₂S₆ catholyte solution for lithium/polysulfides batteries. The fabricated g-C₃N₄/CNTs provide a physical barriers and chemisorption resist polysulfide shuttling. Moreover, the conductive network constructed by CNTs can empower sulfur to be evenly distributed in the cathode and accelerates electron transport. Thus, to further prove the cooperative effect of g-C₃N₄ and CNTs, the freestanding g-C₃N₄/CNTs/Li₂S₆ electrode exhibits more stable electrochemical performance than CNTs/Li₂S₆ electrode, deliver the first discharge capacity of 876 mAh g⁻¹ at 0.5 C and maintained at 633 mAh g⁻¹ after 300 cycles. The sulfur mass in electrode was increased to 7.11 mg, and the g-C₃N₄/CNTs/Li₂S₆ electrode also possess a high capacity retention of 75.5%. Meanwhile, g-C₃N₄ modified CNTs can not only trap polysulfides by strong adsorption but also effectively inhibit the self-discharge behavior of lithium/polysulfides batteries. As a consequence, the g-C₃N₄/CNTs composites for lithium/polysulfides batteries are indicating an excellent electrochemical stability with a long-term storage without obvious capacity degradation.